Nuclear atom model

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Atomic structure

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The Nuclear Atom

The devices we use, the air we breathe, and all other things in the universe are made of matter. This matter is made up of extremely small particles called atoms. These atoms, in turn, are made of particles, which determine the properties of the atom, such as mass and charge, and the way it chemically reacts with other atoms. An atom is not a solid entity; it has a centre and a number of electrons that orbit it in specific locations. This is the definition of a nuclear atom.

It is equally important to understand the nuclear atom for other subjects such as radioactivity, electrical phenomena, and the stability and structure of matter. The nuclear model signifies that most of the mass in an atom is located in the nucleus, while most of its volume is space, since all matter is made up of atoms.

What Is An Atom?

Atoms are the smallest units of an element that keep the element's chemical identity. Each atom contains:

  • Nucleus - the dense center of the atom that contains the majority of the atom's mass.
  • Electron region - the space around the nucleus where the electrons are located.

In the nucleus are large subatomic particles, and electrons are smaller and constantly in motion around the nucleus.

Atoms are key in making up all the chemical and physical properties of matter. An average human hair can contain millions of atoms.

Discovery of Subatomic Particles

Electron

J.J. Thomson discovered the electron in 1897 as he was studying cathode rays. He showed that atoms contain negatively charged particles that are of low mass.

  • Electrons are negatively charged.
  • Their mass is negligible when compared to that of protons and neutrons.
  • They are the particles responsible for the flow of electricity and the chemical bonds between atoms.

The existence of electrons showed that atoms can be broken down into smaller particles.

Discovery of the Nucleus

In 1911, Ernest Rutherford performed the 'gold foil experiment.' He directed alpha particles at a thin gold foil and made three observations:

  • Most of the particles went through the foil without any problems.
  • A small number of the particles were deflected by the foil at small angles
  • Very few particles were reflected back

From these three observations, Rutherford made some conclusions.

  • Atoms are mostly made of space
  • Concentrated in a small, dense nucleus are positive charges and the majority of the atom's mass
  • Electrons are in the outer region of the atom.

As a result of these conclusions, Rutherford created his own atomic model, which dethroned the 'plum pudding' model created by Thomson. The nucleus of an atom includes two key types of subatomic particles:

  • Protons - These particles are positively charged, determine an atom's atomic number and the identity of the element, and reside in the nucleus.
  • Neutrons - These particles have no charge (neutral), contribute to atomic mass and stability of the nucleus, and were discovered in 1932 by James Chadwick.

Structure of the Nuclear Atom

Particle Charge Location Relative Mass
Proton +1 Nucleus ~1 u
Neutron 0 Nucleus ~1 u
Electron −1 Electron cloud ~1/1836 u

Key points of the above table:

  • The nucleus of an atom is extremely small, but almost all of the mass of an atom is found in the nucleus.
  • The nucleus is surrounded by electrons that occupy space, forming an electron cloud.
  • The atom is electrically neutral because the number of protons (positive charge) equals the number of electrons (negative charge).

Atomic Number and Mass Number

Atomic Number (Z) - The number of protons in the nucleus determines the identity of the element. In neutral atoms, the number of protons equals the number of electrons. For example, in the case of Hydrogen, Z=1, in the case of Carbon, Z=6, in the case of Oxygen, Z=8.

Mass Number (A) - The mass number is the total number of protons and neutrons. The mass of electrons is negligible. Thus, A = number of protons + number of neutrons.

Isotopes

Isotopes are atoms of the same element that have an identical number of protons but a different number of neutrons.

All isotopes of an element exhibit the same chemical behavior because they have the same number of electrons arranged in the same way, but they exhibit different physical properties, such as different masses and different nuclear stability.

For example, Carbon-12 and Carbon-14 (both have 6 protons but have a different number of neutrons). Isotopes have many applications, including in the fields of nuclear medicine, research, and radiocarbon dating.

Electron Organization and Levels of Energy

Electrons are found at certain levels of energy (shells) around the center of the atom.

Bohr Model (1913):

  • Electrons travel in distinct energy levels.
  • Inner levels have less energy. Outer levels have more.
  • The most electrons that can be in an energy level are in the range of 2, 8, 18.
  • Levels determine the chemical reactivity of the atom and the types of bonds that can be made with other atoms.

Modern Quantum Model:

  • Electrons are found in orbitals.
  • The location of an electron cannot be determined (Heisenberg).
  • More accurately describes the behavior of the atom and the bonds that can be made than other models.
  • Quantum mechanics explains why atoms emit certain types of energy.

Stability and Nuclear Forces

Positively charged protons repel each other in the nucleus, but the nuclear force can counter this:

  • Nuclear force is extremely strong but works at very short distances, only 10^-15.
  • The nuclear force binds protons and neutrons and keeps the atom from falling apart.
  • Radioactive decay is when an unstable nucleus decays and emits energy in the form of radiation.

Ions and Atomic Charge

Ions are formed when an atom loses or gains electrons.

  • When an atom loses electrons, a positive ion (cation) is formed.
  • When an atom gains electrons, a negative ion (anion) is formed.
  • The identity of the element does not change because the number of protons is still the same.

Ions are very important in the study of electricity, electrochemistry, and chemical reactivity.

Significance of the Nuclear Atom

Nuclear atoms aid our understanding of:

  • Matter's structure & chemical reactions
  • The structure of the periodic table
  • The concepts of electricity, bonding, & conductivity
  • The nuclear energy & its medical applications

Examples include:

  • Protons define the element
  • Electrons define chemical behavior
  • Neutrons define mass & stability

Without such understanding, one can not comprehend modern chemistry, physics, & nuclear science.

Overview

The nuclear atom model represents an atom as a nucleus, dense with protons & neutrons, with surrounding electrons arranged in layers of quantized energy. This structure accounts for the identity, mass, chemical behavior, & nuclear stability of an element.