Particle nature of matter

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Particle model

DP Chemistry

Particle Nature of Matter

Every substance in the observable universe, whether it is as common as air or as complex as biological organisms, is made of tiny, discrete particles. Even though these fundamental particles are too tiny to see, they still determine the observable properties and behaviors of matter. A solid understanding of these interactions explains why some substances are denser than others, why they can change from one state to another, and why they react chemically. The particle model is one of the more important models in Chemistry as it is used to explain the different behaviors of matter at the atomic and molecular level.

What is the matter?

Matter is anything that has mass and takes up space. This includes all solids, liquids, and gases. All matter is made up of atoms and molecules, which are:

  • Very small
  • Have mass
  • Are always moving
  • Have space between them
  • Intermolecular forces balance between attraction and repulsion

While we cannot see individual particles of matter, we can see and measure their collective behaviors, which we can then describe in terms of matter's physical and chemical properties.

The Particle Model of Matter

The particle model gives us a good explanation of matter's behavior on a microscopic scale:

  • Matter is made of particles
  • All particles are always moving
  • The average energy and speed of particles are directly related to their temperature
  • There is space between particles even when particles are packed closely together
  • The behavior of particles is governed by forces acting on them

This theory helps us to understand phenomena like:

  • Phase changes (i.e., when ice melts to become water, then warms to become steam)
  • The ability of liquids and gases to spread out (diffusion)
  • The ability of matter to expand when heated (thermal expansion)
  • The ability of some matter to be made less dense by increasing temperature (compressibility)

Atoms - The Basic Units of Matter

An atom is the smallest unit of an element that still has the chemical properties of that element. Atoms are very, very small; about 1 x 10^-10 meters. It is not possible to see individual atoms with a light microscope. The special type of microscope that permits direct viewing of individual atoms is a scanning tunneling microscope (STM) or an electron microscope. Some examples of atoms include:

  • Oxygen in O₂
  • Iron in metallic lattices
  • Carbons in organic compounds

Atoms form the fundamental basis of all substances and the basis for molecular design and chemical activity.

Molecules: Structures Designed from Atoms

Molecules come from the chemical connection of 2 or more of the same or different atoms.

Some instances include:

  • Oxygen (O₂) molecule
  • Water (H₂O) molecule
  • Carbon dioxide (CO₂) molecule

The structure of the molecule controls its physical and chemical characteristics of the molecule. This includes polarity, reaction, and what phase the molecule exists in. Most substances that occur in nature exist in multiple molecular arrangements.

Solid State

  • The structure of the molecules in solids is arranged in rigid, crystalline arrangements.
  • Because of this, the particles are very closely bonded to each other.
  • While in this state, the molecules are only allowed to vibrate.
  • Iron, diamond, and ice are all examples of solids.

Liquid State

  • In this state, the particles are also closely bonded; however, they are allowed to slide over each other.
  • This is a result of the reduction of the bonds that hold the molecules in a rigid structure.
  • While in a liquid state, the molecules are held in a solution in a definite volume; however, they will take the shape of the container that they are held in.

Gas State

  • In a gaseous state, the molecules are only loosely held together, and they are allowed to move independently.
  • High Motion and Energy
  • The particles have negligible intermolecular forces, and there is no arrangement or fixed shape. They also have an elastic volume.
  • Examples include Oxygen and Carbon Dioxide.

Kinetic Energy and Motion of Particles

The motion of the particles known as kinetic motion, contributes to thermal energy. The motion of particles (which is what defines thermal energy) is an indicator of how much kinetic energy there is. This defines how much motion there is. All particles are always in motion, and the more you add to the temperature, the more kinetic energy there is, which also defines the more motion there is. The lower the temperature, the less motion.

The motion of the particles is what defines thermal expansion; the motion defines the kinetic energy of what is in the container, which also defines the more motion there is.

Behavior of Particles and States of Matter

The motion of the particles is what defines the state of the particles. There is a change in energy transfer, while the particles remain the same. This is called phase change.

Some common examples include:

  • Melting: Solid to liquid
  • Freezing: Liquid to solid
  • Boiling: Liquid to gas
  • Condensation: Gas to liquid

Diffusion

Diffusion is the random movement of particles. There is movement from one area, and then it is concentrated in one area, while the surrounding area is less.

Examples include:

  • The smell of a ship, the smell of food that was made, and perfume that is sprayed in the air.

Diffusion from Solid to Liquid to Gas is the fastest in that order.

The Evidence of the Particle Model

The experimental and observational evidence also supports the particle model. The evidence for the various aspects of the particle model includes the following:

  • Diffusion demonstrates the motion of particles,
  • Thermal expansion shows that particles expand,
  • The compressibility of gases emphasized that particles can move,
  • Phase transitions illustrate that particles rearrange and adjust based on the energy of the system.

The evidence supports the fundamental aspects of matter.

Density and the Arrangement of Particles

The equation for density states:

Density = Mass / Volume

Density also describes how particles are arranged:

  • The more particles that are packed together, the greater the density,
  • The more that particles are packed apart, the lower the density.
  • Solids are particles that are most densely packed,
  • Liquids are particles that are less densely packed than solids,
  • Gases are particles that are the least densely packed.

The arrangement of particles explains the following:

  • Buoyant life,
  • The strength of the material, and
  • Behavior in different phases

The Conservation of Matter and the Integrity of Particles

The law of conservation of matter states that matter cannot be created or destroyed in any physical change.

In melting, boiling, or freezing, the number of particles stays the same. Only the arrangement of these particles in space and the kinetic energy of the particles change. The total mass of the system is conserved.

Importance of the Particle Model

The particle model is one of the most essential models as it allows one to explain and predict the following:

  • Phase changes and thermodynamic behavior,
  • The effect of temperature changes on matter,
  • The behavior of gases and their compressibility,
  • The diffusion and mixing of gases,
  • The mechanisms of chemical reactions.

To understand the behavior of matter at the particle level is essential to facilitate sophisticated chemical analysis and molecular modeling.

The Particle Model Summary

Here are the key principles:

  • Matter is made up of individual particles
  • All particles are always moving
  • There is spacing between particles, and forces act between them
  • Motion of particles is dependent on the temperature
  • Arrangement of particles determines the state and density of matter
  • Microscopic behavior is the cause of macroscopic behavior

For Chemistry, the Particle Model helps explain how Chemistry and Physics interact on a molecular and atomic level.